首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2297篇
  免费   117篇
  国内免费   279篇
化学   621篇
晶体学   1篇
力学   128篇
综合类   45篇
数学   1721篇
物理学   177篇
  2024年   2篇
  2023年   21篇
  2022年   33篇
  2021年   119篇
  2020年   65篇
  2019年   84篇
  2018年   94篇
  2017年   74篇
  2016年   94篇
  2015年   97篇
  2014年   87篇
  2013年   222篇
  2012年   80篇
  2011年   77篇
  2010年   83篇
  2009年   116篇
  2008年   140篇
  2007年   147篇
  2006年   133篇
  2005年   123篇
  2004年   103篇
  2003年   105篇
  2002年   115篇
  2001年   75篇
  2000年   75篇
  1999年   52篇
  1998年   60篇
  1997年   42篇
  1996年   22篇
  1995年   22篇
  1994年   20篇
  1993年   12篇
  1992年   8篇
  1991年   12篇
  1990年   5篇
  1989年   10篇
  1988年   4篇
  1987年   3篇
  1986年   7篇
  1985年   9篇
  1984年   8篇
  1983年   3篇
  1982年   13篇
  1981年   5篇
  1980年   5篇
  1979年   3篇
  1978年   2篇
  1977年   1篇
  1976年   1篇
排序方式: 共有2693条查询结果,搜索用时 49 毫秒
91.
By application of the method of complex variable function, dynamic extension problems on the surfaces of asymmetrical mode III crack subjected to shear loads were researched. Universal expressions of analytical solutions were attained by the approaches of self-similar functions. The problems considered can be facilely transformed into Riemann–Hilbert problems in terms of this technique, and analytical solutions of the stress, the displacement and dynamic stress intensity factor under the actions of unlike loads P and Pt located at the origin of the coordinates respectively, were acquired. In the light of corresponding material properties, the variable rule of dynamic stress intensity factor was depicted very well. By those solutions gained and superposition principle, the solutions of discretionarily intricate problems can be obtained.  相似文献   
92.
利用C_0-半群理论证明了具有一种故障类型的二相关单元冗余系统非负解的存在惟一性,并研究了相应算子的谱特征,通过分析本质谱界经过紧扰动后的变化,得到了系统动态解以指数形式收敛于稳态解.最后,给出几个数值模拟的例子用来说明本文的意义所在.  相似文献   
93.
The energy release rate criterion, being mono scale by definition, is incompatible with the failure behavior of solids that are inherently dual, if not, multiscale. Time span of reliability is scale sensitive and can be addressed with consistency only by use of transitional functions that are designed to transform a function from one scale to another. A pseudo transitional energy release rate G is defined to address the cross-scaling properties of energy release rate. The reliability of such a function is found to fall quickly when the scale range deviates from that of micro-macro. In general, the time span of reliability based on G* shortens considerably within the nano-micro and pico-nano scale ranges, resulting in fast turnover of system usability. Prediction accuracy tends to be scale range specific. Stress or strain based criteria are also mono scale. They may be adequate for some situations at the macroscopic scale, but can be ambiguous for multiscale problems. These situations are analyzed by application of the principle of least variance in conjunction with the R-integrals.Accelerated test data for the equivalent of 20 years’ fatigue crack growth in 2024-T3 aluminum panels were analyzed using the mutliscale reliability model. A time span plateau within the micro-macro range is from 8 to 17 years. This corresponds to the reliable portion of prediction, while the terminal 3 years are regarded as unreliable. A similar time span plateau were also found from 4 to 6 years within the nano-micro scale range. And an even smaller plateau hovering around 1.2 years were found for the pico-nano scale range. Time span of reliable prediction narrows with down sized scale range. The overlapping ends of the scale ranges are rendered unreliable as anticipated. These regions can be suppressed by the addition of meso scale ranges. Reference can be made to past discussions related to multiscaling and mesomechanics.  相似文献   
94.
Flavours and fragrances are volatile compounds of large interest for different applications. Due to their high tendency of evaporation and, in most cases, poor chemical stability, these compounds need to be encapsulated for handling and industrial processing. Encapsulation, indeed, resulted in being effective at overcoming the main concerns related to volatile compound manipulation, and several industrial products contain flavours and fragrances in an encapsulated form for the final usage of customers. Although several organic or inorganic materials have been investigated for the production of coated micro- or nanosystems intended for the encapsulation of fragrances and flavours, polymeric coating, leading to the formation of micro- or nanocapsules with a core-shell architecture, as well as a molecular inclusion complexation with cyclodextrins, are still the most used. The present review aims to summarise the recent literature about the encapsulation of fragrances and flavours into polymeric micro- or nanocapsules or inclusion complexes with cyclodextrins, with a focus on methods for micro/nanoencapsulation and applications in the different technological fields, including the textile, cosmetic, food and paper industries.  相似文献   
95.
建立了基于光电准直原理的姿态角测量系统,提出一种虚拟扩展成像面技术,应用于测量系统中,对图像传感器成像面进行复用,虚拟扩大系统的测量视场.介绍了系统的主要工作原理,在系统模型下,对可能影响系统测量精度的误差源进行了分析,建立其数学关系,对精度影响因素进行了定量仿真实验.按照仿真结果,对系统设计方案进行了分析验证.结果表...  相似文献   
96.
The purpose of this study was to develop and test a diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) method, a fast and non-destructive method without extraction, and compare it with the standard gas chromatography (GC) method currently used. A micro-orifice uniform deposit impactor (MOUDI) was used to sample all the size distributions of the aerosol particles of essential oils to investigate the relation between size distributions and the indoor concentration distributions of ylang essential oils. Correlation coefficients for DRIFTS and GC were 0.9904, 0.9910, 0.9913, and 0.9983 for eugenol, isoeugenol, methyl ether, and eugenyl acetate, respectively. The results showed that the concentrations of the four eugenol derivatives of smoke were approximately three times higher than those of mist. Additionally, the major size distributions of aerosol were 0.19 μm and 1.8 μm for the smoke and mist methods, respectively. Because these two methods produce similar results, DRIFTS is a practical method for assessing these fragrances in aerosols.  相似文献   
97.
The essential oil of the leaves of Cupressus sempervirens L. was isolated by hydrodistillation and tested against gram positive and gram negative bacteria, showing remarkable antimicrobial activity against Bacillus subtilis with minimum inhibitory concentration (MIC) 75%. The antiviral activity of the essential oil was tested against Herpes simplex virus type 1 (HSV-1), showing antiviral activity with virucidal percentages of 68.0% and 53.2% at concentrations of 1:32 and 1:64, respectively. We firstly reported the isolation of two epi-betulin esters of fatty acids from the CHCl3 fraction of Cupressus sempervirens L. leaves, which were isolated and purified using HPLC, and identified using PMR and MS. The CHCl3 fraction showed significant cytotoxicity against HeLa cells. Published in Khimiya Prirodnykh Soedinenii, No. 3, pp. 265–268, May–June, 2009.  相似文献   
98.
Polymeric methylene diphenyl diisocyanate (PMDI) was added as chain extender to a blend of recycled poly(ethylene terephthalate) (R-PET) and linear low density polyethylene (LLDPE) with compatibilizer of maleic anhydride-grafted poly(styrene-ethylene/butadiene-styrene) (SEBS-g-MA). Hydroxyl end groups of PET can react with both isocyanate groups of PMDI and maleic anhydride groups of SEBS-g-MA, which are competing reactions during reactive extrusion. The compatibility and properties of the blends with various contents of PMDI were systemically evaluated and investigated. WAXD results and SEM observations indicated that chain extension inhibits the reaction between PET and SEBS-g-MA. As the PMDI content increased, the morphology of dispersed phase changed from droplet dispersion to rodlike shape and then to an irregular structure. The DSC results showed that the crystallinity of PET decreased in the presence of PMDI, and the glass transition temperature (Tg) of PET increased with addition of 0-0.7 w% PMDI. The impact strength of the blend with 1.1 w% PMDI increased by 120% with respect to the blend without PMDI, accompanied by only an 8% tensile strength decrease. It was demonstrated that the chain extension of PET with PMDI in R-PET/LLDPE/SEBS-g-MA blends not only decreased the compatibilization effect of SEBS-g-MA but also hindered the crystallization of PET.  相似文献   
99.
Kre?n's formula provides a parametrization of the generalized resolvents and Štraus extensions of a closed symmetric operator with equal possibly infinite defect numbers in a Hilbert space in terms of Nevanlinna families in a parameter space. The aim of this note is to give a simple complete analytical proof of Kre?n's formula.  相似文献   
100.
Sufficient conditions are presented for super/weak Poincare inequalities to hold for a class of hypoelliptic operators on noncompact manifolds. As applications, the essential spectrum and the convergence rate of the associated Markov semigroup are described for Gruschin type operators on R2 and Kohn-Laplacian type operators on the Heisenberg group.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号